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玻璃中的热导率、弛豫和低频振动模式异常:一种使用费米-帕斯塔-乌拉姆非线性哈密顿量的模型

Thermal conductivity, relaxation and low-frequency vibrational mode anomalies in glasses: a model using the Fermi-Pasta-Ulam nonlinear Hamiltonian.

作者信息

Romero-Arias J R, Salazar F, Naumis G G, Fernandez-Anaya G

机构信息

Departamento de Física-Química, Instituto de Física, Universidad Nacional Autónoma de México (UNAM), Apartado Postal 20-364, 01000 México, Distrito Federal, Mexico.

出版信息

Philos Trans A Math Phys Eng Sci. 2009 Aug 28;367(1901):3173-81. doi: 10.1098/rsta.2009.0069.

Abstract

We present a nonlinear model that allows exploration of the relationship between energy relaxation, thermal conductivity and the excess of low-frequency vibrational modes (LFVMs) that are present in glasses. The model is a chain of the Fermi-Pasta-Ulam (FPU) type, with nonlinear second neighbour springs added at random. We show that the time for relaxation is increased as LFVMs are removed, while the thermal conductivity diminishes. These results are important in order to understand the role of the cooling speed and thermal conductivity during glass transition. Also, the model provides evidence for the fundamental importance of LFVMs in the FPU problem.

摘要

我们提出了一个非线性模型,该模型可用于探究能量弛豫、热导率与玻璃中存在的低频振动模式(LFVM)过剩之间的关系。该模型是费米-帕斯塔-乌拉姆(FPU)型链,随机添加了非线性次近邻弹簧。我们表明,随着LFVM的去除,弛豫时间增加,而热导率降低。这些结果对于理解玻璃转变过程中冷却速度和热导率的作用很重要。此外,该模型为LFVM在FPU问题中的根本重要性提供了证据。

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