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新合成的吡啶-3-甲腈给体-受体生色团的荧光性质。

Fluorescence properties of donor acceptor chromophores on newly synthesized pyridine-3-carbonitriles.

机构信息

Department of Chemistry, Organic Chemistry Research Centre, KTHM College, Gangapur Road, Nashik, MS, India.

出版信息

J Fluoresc. 2009 Nov;19(6):1119-24. doi: 10.1007/s10895-009-0511-x. Epub 2009 Jul 22.

Abstract

A convenient route was successfully developed for the synthesis of novel heterocycles such as pyridine-3-carbonitriles 4 from chalcone 3 in good yields. The pyridine-3-carbonitrile derivatives synthesized were further studied for their photophysical properties and observed that absorption and emission was changed, due to the chromospheres at C4-position in phenyl ring and C2-position in pyridine-3-carbonitrile derivatives.

摘要

成功开发了一条从查尔酮 3 合成新型杂环化合物如吡啶-3-甲腈 4 的便捷路线,产率良好。进一步研究了合成的吡啶-3-甲腈衍生物的光物理性质,观察到由于苯环的 C4 位和吡啶-3-甲腈衍生物的 C2 位的取代基,吸收和发射发生了变化。

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