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取代基对噻吩并[3,2-c]吡啶衍生物吸收和荧光性质的影响

Substituent Effect on Absorption and Fluorescence Properties of Thieno[3, 2-c]Pyridine Derivatives.

作者信息

Chavan Sunil N, Toche Raghunath B, Chavan Satish M

机构信息

Department of Chemistry, KRT Arts BH Commerce & AM Science College, Gangapur Road Shivajinagar, Nashik, Maharashtra, -422002, India.

Savitribai Phule Pune University (Formerly University of Pune), Pune, Maharashtra, -411007, India.

出版信息

J Fluoresc. 2017 Mar;27(2):443-450. doi: 10.1007/s10895-017-2026-1. Epub 2017 Jan 21.

Abstract

New substituted thieno[3,2-c]pyridine derivatives 5 were synthesized by the reaction of 3-bromo-4-chlorothieno[3,2-c]pyridine 1 with cyclic amine 2, which further on Suzuki reaction with boronic acids 4 converted to corresponding 3-arylthieno[3,2-c]pyridine 5. Substituent R has predominant effect on fluorescence properties of thienopyridines. However, the electron donor amine at C has no effect on fluorescence properties of thienopyridines. Graphical Abstract New thieno[3,2-c]pyridine derivatives were synthesized from 3-bromo-4-chlorothieno[3,2-c]pyridine and cyclic amines, which by on Suzuki reaction with boronic acids converted to corresponding 3-arylthieno[3,2-c]pyridine. Substituent R3 has predominant effect on fluorescence properties of thienopyridines. However, the electron donor amine at C4 has no effect on fluorescence properties of thienopyridines.

摘要

通过3-溴-4-氯噻吩并[3,2-c]吡啶1与环胺2反应合成了新型取代噻吩并[3,2-c]吡啶衍生物5,其再与硼酸4进行铃木反应转化为相应的3-芳基噻吩并[3,2-c]吡啶5。取代基R对噻吩并吡啶的荧光性质有主要影响。然而,C位的给电子胺对噻吩并吡啶的荧光性质没有影响。图形摘要 新型噻吩并[3,2-c]吡啶衍生物由3-溴-4-氯噻吩并[3,2-c]吡啶和环胺合成,其通过与硼酸进行铃木反应转化为相应的3-芳基噻吩并[3,2-c]吡啶。取代基R3对噻吩并吡啶的荧光性质有主要影响。然而,C4位的给电子胺对噻吩并吡啶的荧光性质没有影响。

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