Polymer Science and Engineering Department, University of Massachusetts, Amherst, Massachusetts 01003, USA.
Langmuir. 2009 Dec 15;25(24):14105-15. doi: 10.1021/la902206c.
We review our 2006-2009 publications on wetting and superhydrophobicity in a manner designed to serve as a useful primer for those who would like to use the concepts of this field. We demonstrate that the 1D (three-phase, solid/liquid/vapor) contact line perspective is simpler, more intuitive, more useful, and more consistent with facts than the disproved but widely held-to-be-correct 2D view. We give an explanation of what we believe to be the reason that the existing theoretical understanding is wrong and argue that the teaching of surface science over the last century has led generations of students and scientists to a misunderstanding of the wetting of solids by liquids. We review our analyses of the phenomena of contact angle hysteresis, the lotus effect, and perfect hydrophobicity and suggest that needlessly complex theoretical understandings, incorrect models, and ill-defined terminology are not useful and can be destructive.
我们回顾了我们在 2006 年至 2009 年期间发表的关于润湿和超疏水的论文,旨在为那些希望使用这一领域概念的人提供有用的入门知识。我们证明,1D(三相,固/液/气)接触线视角比已被证明错误但被广泛认为是正确的 2D 观点更简单、更直观、更有用,也更符合事实。我们解释了为什么现有的理论理解是错误的,并认为过去一个世纪的表面科学教学导致了几代学生和科学家对液体润湿固体的误解。我们回顾了对接触角滞后、荷叶效应和完全疏水性现象的分析,并提出不必要的复杂理论理解、不正确的模型和不明确的术语是没有用的,甚至可能具有破坏性。