一维平行富勒烯排列的α,γ-肽纳米管模板化

Alpha,gamma-peptide nanotube templating of one-dimensional parallel fullerene arrangements.

作者信息

Reiriz César, Brea Roberto J, Arranz Rocío, Carrascosa José L, Garibotti Alejandra, Manning Brendan, Valpuesta José M, Eritja Ramón, Castedo Luis, Granja Juan R

机构信息

Departamento de Química Orgánica, Universidad de Santiago de Compostela, E-15782 Santiago de Compostela, Spain.

出版信息

J Am Chem Soc. 2009 Aug 19;131(32):11335-7. doi: 10.1021/ja904548q.

DOI:10.1021/ja904548q

PMID:19630409

Abstract

The formation and full characterization of single self-assembling alpha,gamma-peptide nanotubes (alpha,gamma-SPNs) is described. The introduction of C(60) into cyclic peptides allows the preparation of supramolecular 1D fullerene arrangements induced by peptide nanotube formation under appropriate conditions.

摘要

描述了单自组装α，γ-肽纳米管（α，γ-SPNs）的形成及完整表征。将C(60)引入环肽中，能够在适当条件下通过肽纳米管的形成诱导制备超分子一维富勒烯排列。