Silesian University of Technology, Faculty of Chemistry, 44-100 Gliwice, Poland.
J Hazard Mater. 2009 Nov 15;171(1-3):1175-7. doi: 10.1016/j.jhazmat.2009.06.104. Epub 2009 Jun 26.
Ten transition metal nitrate and perchlorate complexes of hydrazine and ethylenediamine were synthesized, namely Cu(EN)(2)(2), Co(EN)(3)(3), Ni(EN)(3)(2), Hg(EN)(2)(2), Cr(N(2)H(4))(3)(3), Cd(N(2)H(4))(3)(2), Ni(N(2)H(4))(3)(2), Co(N(2)H(4))(3)(3), Zn(N(2)H(4))(3)(2), and Cd(N(2)H(4))(3)(2) based on the lines of the literature reported methods. All of them were tested with applying underwater detonation test and further compared to the typical blasting explosives: RDX, HMX, TNT and PETN. From the above presented complexes Ni(N(2)H(4))(3)(2) (called NHN) and Co(N(2)H(4))(3)(3) (called CoHN) are known as primary explosives and can be used as the standard explosives. Explosion parameters, such as shock wave overpressure, shock wave energy equivalent and bubble energy equivalent, were determined. Evaluated energetic characteristics of the tested compounds are comparable to those of the classic high explosives and are even enhanced in some cases.
合成了十种过渡金属硝酸盐和高氯酸盐与肼和乙二胺的配合物，即Cu(EN)(2)(2)、Co(EN)(3)(3)、Ni(EN)(3)(2)、Hg(EN)(2)(2)、Cr(N(2)H(4))(3)(3)、Cd(N(2)H(4))(3)(2)、Ni(N(2)H(4))(3)(2)、Co(N(2)H(4))(3)(3)、Zn(N(2)H(4))(3)(2)和Cd(N(2)H(4))(3)(2)，方法基于文献报道的路线。所有这些都经过水下爆炸试验测试，并与典型的爆炸物：RDX、HMX、TNT 和 PETN 进一步比较。在所呈现的配合物中，Ni(N(2)H(4))(3)(2)（称为 NHN）和Co(N(2)H(4))(3)(3)（称为 CoHN）是已知的起爆药，可以用作标准炸药。确定了爆炸参数，如冲击波超压、冲击波能量当量和气泡能量当量。评估了测试化合物的能量特性，这些特性与经典高能炸药相当，在某些情况下甚至得到了增强。
