Kalogirou Andreas S, Koutentis Panayiotis A
Department of Chemistry, University of Cyprus, P.O. Box 20537, 1678 Nicosia, Cyprus.
Molecules. 2009 Jul 2;14(7):2356-62. doi: 10.3390/molecules14072356.
N-Aryl-S,S-dimethylsulfimides 3(Ar = 4-NO(2)C(6)H(4)), 4 (Ar = Ph) and 5 (Ar = 4-Tol)react with Appel salt 1 to give the corresponding N-aryl-(4-chloro-5H-1,2,3-dithiazolylidene)benzenamines 8 (Ar = 4-NO(2)C(6)H(4)), 9 (Ar = Ph) and 10 (Ar = 4-Tol) in 84, 94 and 87% yields, respectively. The reaction proceeds in the absence of base and a proposed reaction mechanism is given.
N-芳基-S,S-二甲基硫酰亚胺3（Ar = 4-NO₂C₆H₄）、4（Ar = Ph）和5（Ar = 4-Tol）与阿佩尔盐1反应，分别以84%、94%和87%的产率得到相应的N-芳基-（4-氯-5H-1,2,3-二噻唑亚基）苯甲胺8（Ar = 4-NO₂C₆H₄）、9（Ar = Ph）和10（Ar = 4-Tol）。该反应在无碱条件下进行，并给出了一个可能的反应机理。
