Lan Xinwei, Han Yukun, Wei Tao, Zhang Yinan, Jiang Lan, Tsai Hai-Lung, Xiao Hai
Department of Electrical and Computer Engineering, Missouri University of Science and Technology, 1870 Miner Circle, Rolla, Missouri 65409, USA.
Opt Lett. 2009 Aug 1;34(15):2285-7. doi: 10.1364/ol.34.002285.
We report what we believe to be a new method to fabricate surface enhanced Raman scattering (SERS) fiber probe by direct femtosecond laser micromachining. Direct femtosecond laser ablations resulted in nanostructures on the cleaved endface of a multimode optical fiber with a 105/125 microm core/cladding diameter. The laser-ablated fiber endface was SERS activated by silver chemical plating. High-quality SERS signal was detected using Rhodamine 6G molecules (10(-8)-10(-6) M solutions) via back excitation with the fiber length of up to 1 m. The fiber SERS probe was compared with a planar fused silica substrate at a front excitation. The long lead-in fiber length and the backexcitation/collection setup make the SERS probe promising for remote sensing applications.
我们报道了一种我们认为通过直接飞秒激光微加工制造表面增强拉曼散射(SERS)光纤探针的新方法。直接飞秒激光烧蚀在芯径/包层直径为105/125微米的多模光纤的切割端面上产生了纳米结构。通过银化学镀对激光烧蚀的光纤端面进行SERS激活。使用罗丹明6G分子(10^(-8)-10^(-6) M溶液)通过光纤长度达1米的背向激发检测到了高质量的SERS信号。在正向激发下,将光纤SERS探针与平面熔融石英衬底进行了比较。长的引入光纤长度和背向激发/收集设置使SERS探针在遥感应用方面具有前景。