Prasad K Eswar, Das Barun, Maitra Urmimala, Ramamurty Upadrasta, Rao C N R
Department of Materials Engineering, Indian Institute of Science, Bangalore-560012, India.
Proc Natl Acad Sci U S A. 2009 Aug 11;106(32):13186-9. doi: 10.1073/pnas.0905844106. Epub 2009 Jul 27.
One of the applications of nanomaterials is as reinforcements in composites, wherein small additions of nanomaterials lead to large enhancements in mechanical properties. There have been extensive studies in the literature on composites where a polymer matrix is reinforced by a single nanomaterial such as carbon nanotubes. In this article, we examine the significant synergistic effects observed when 2 different types of nanocarbons are incorporated in a polymer matrix. Thus, binary combinations of nanodiamond, few-layer graphene, and single-walled nanotubes have been used to reinforce polyvinyl alcohol. The mechanical properties of the resulting composites, evaluated by the nanoindentation technique, show extraordinary synergy, improving the stiffness and hardness by as much as 400% compared to those obtained with single nanocarbon reinforcements. These results suggest a way of designing advanced materials with extraordinary mechanical properties by incorporating small amounts of 2 nanomaterials such as graphene plus nanodiamond or nanodiamond plus carbon nanotube.
纳米材料的应用之一是作为复合材料中的增强剂,其中少量添加纳米材料会使机械性能大幅提高。关于聚合物基体由单一纳米材料(如碳纳米管)增强的复合材料,文献中已有广泛研究。在本文中,我们研究了将两种不同类型的纳米碳掺入聚合物基体时观察到的显著协同效应。因此,纳米金刚石、少层石墨烯和单壁纳米管的二元组合已被用于增强聚乙烯醇。通过纳米压痕技术评估所得复合材料的机械性能,结果显示出非凡的协同效应,与使用单一纳米碳增强剂相比,刚度和硬度提高了多达400%。这些结果表明了一种通过掺入少量两种纳米材料(如石墨烯加纳米金刚石或纳米金刚石加碳纳米管)来设计具有非凡机械性能的先进材料的方法。