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本文引用的文献

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Mono-oxo bis(dithiolene) Mo(IV)/W(IV) complexes as building blocks for sulfide bridged Bi- and Tri-nuclear complexes.单氧代双（二硫烯）钼（IV）/钨（IV）配合物作为硫化物桥联双核和三核配合物的构建单元。
Inorg Chem. 2008 Jun 16;47(12):5360-4. doi: 10.1021/ic800466x. Epub 2008 May 10.
2
Heterospin systems constructed from [Cu2Ln]3+ and [Ni(mnt)2]1-,2- Tectons: First 3p-3d-4f complexes (mnt = maleonitriledithiolato).由[Cu2Ln]3+和[Ni(mnt)2]1-、2-构筑单元构建的异自旋体系：首例3p-3d-4f配合物（mnt = 马来二腈二硫醇盐）
Inorg Chem. 2008 Feb 4;47(3):940-50. doi: 10.1021/ic701738z. Epub 2008 Jan 3.
3
Mechanistic investigation of the oxygen-atom-transfer reactivity of dioxo-molybdenum(VI) complexes.二氧代钼（VI）配合物氧原子转移反应活性的机理研究
Chemistry. 2006 Sep 25;12(28):7501-9. doi: 10.1002/chem.200600269.
4
Synthesis, molecular and electronic structure, and TDDFT and TDDFT-PCM study of the solvatochromic properties of (Me2Pipdt)Mo(CO)4 complex (Me2Pipdt = N,N'-dimethylpiperazine-2,3-dithione).（Me2Pipdt）Mo（CO）4配合物（Me2Pipdt = N，N'-二甲基哌嗪-2,3-二硫酮）的溶剂化显色性质的合成、分子与电子结构以及TDDFT和TDDFT-PCM研究
Inorg Chem. 2006 May 1;45(9):3557-68. doi: 10.1021/ic051653p.
5
Rotational barrier of a molybdenum-molybdenum quadruple bond.钼-钼四重键的旋转势垒。
Proc Natl Acad Sci U S A. 1984 Apr;81(8):2592-6. doi: 10.1073/pnas.81.8.2592.
6
A family of oxo-chalcogenide molybdenum and tungsten complexes, (n-Bu4N)2[M2O2(mu-Q)2(1,3-dithiole-2-thione-4,5-dithiolate)2] (M = Mo, W; Q = S, Se): new synthetic entries, structure, and gas-phase behavior.一族氧代硫属化物钼和钨配合物，(正丁基)4N)2[M2O2(μ-Q)2(1,3-二硫杂环戊烯-2-硫酮-4,5-二硫醇盐)2]（M = 钼，钨；Q = 硫，硒）：新的合成方法、结构及气相行为
Inorg Chem. 2005 Nov 28;44(24):8937-46. doi: 10.1021/ic0508728.
7
Proton induced P-H and Mo-H bond activation at the phosphide bridged dimolybdenum complexes [Mo2Cp2(mu-H)(mu-PHR)(CO)4](R = Cy, 2,4,6-C6H2R'3; R'= H, Me, tBu).质子诱导磷桥联二钼配合物[Mo₂Cp₂(μ-H)(μ-PHR)(CO)₄](R = 环己基, 2,4,6-三取代苯基; R' = H, 甲基, 叔丁基)中的P-H和Mo-H键活化
Dalton Trans. 2004 Dec 21(24):4168-79. doi: 10.1039/b412875c. Epub 2004 Nov 15.
8
Conducting metal dithiolene complexes: structural and electronic properties.导电金属二硫纶配合物：结构与电子性质
Chem Rev. 2004 Nov;104(11):5319-46. doi: 10.1021/cr030655t.
9
Electronic factors affecting second-order NLO properties: case study of four different push-pull bis-dithiolene nickel complexes.影响二阶非线性光学性质的电子因素：四种不同推拉型双二硫纶镍配合物的案例研究
Inorg Chem. 2004 Aug 9;43(16):5069-79. doi: 10.1021/ic0496469.
10
A bifurcated pathway of oxygen atom transfer reactions from a monooxo molybdenum(VI) complex under electrospray ionisation mass spectrometric conditions.在电喷雾电离质谱条件下，单氧钼（VI）配合物中氧原子转移反应的分叉途径。
Dalton Trans. 2004 Jul 7(13):1928-33. doi: 10.1039/b403964e. Epub 2004 Jun 1.

由二硫酮配体稳定的低配位脱氧钼簇合物的合成、表征及结构

Synthesis, characterization and structure of a low coordinate desoxomolybdenum cluster stabilized by a dithione ligand.

作者信息

Perera Eranda, Basu Partha

机构信息

Department of Chemistry and Biochemistry, Duquesne University, Pittsburgh, PA 15282, USA.

出版信息

Dalton Trans. 2009 Jul 7(25):5023-8. doi: 10.1039/b904113c. Epub 2009 May 27.

DOI:10.1039/b904113c
PMID:19662295
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2894468/
Abstract

Using an oxidized state of a dithiolene ligand, diisopropylpiperazine-2,3-dithione (i-Pr(2)Pipdt), two monooxo-molybdenum complexes have been synthesized. From one of them, a desoxomolybdenum cluster, (i-Pr(2)Pipdt)MoBF(4) has been prepared. The molecular structure of this cluster reveals metal-metal interactions and weak coordination by the BF(4) anion.

摘要

利用二硫纶配体二异丙基哌嗪 -2,3 - 二硫酮（i-Pr₂Pipdt）的氧化态，合成了两种单氧钼配合物。从其中一种配合物中制备出了一种脱氧钼簇合物[(i-Pr₂Pipdt)Mo]₄[BF₄]₄。该簇合物的分子结构揭示了金属 - 金属相互作用以及BF₄⁻阴离子的弱配位作用。