铑催化的由三乙基硼促进的醛与共轭二烯的还原偶联反应。
Rh-catalyzed reductive coupling reaction of aldehydes with conjugated dienes promoted by triethylborane.
作者信息
Kimura Masanari, Nojiri Daisuke, Fukushima Masahiro, Oi Shuichi, Sonoda Yusuke, Inoue Yoshio
机构信息
Department of Applied Chemistry, Faculty of Engineering, Nagasaki University, 1-14 Bunkyo-machi, Nagasaki 852-8521, Japan.
出版信息
Org Lett. 2009 Sep 3;11(17):3794-7. doi: 10.1021/ol901527b.
PMID:19663391
Abstract
Rh(I) catalyzes the reductive coupling reaction of a wide variety of aldehydes with conjugated dienes in the presence of a stoichiometric amount of triethylborane to provide homoallyl alcohols in a single operation.
摘要
铑（I）在化学计量的三乙基硼存在下，催化多种醛与共轭二烯的还原偶联反应，可一步合成高烯丙醇。
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