Nishikata Takashi, Lipshutz Bruce H
Department of Chemistry & Biochemistry, University of California, Santa Barbara, California 93106, USA.
J Am Chem Soc. 2009 Sep 2;131(34):12103-5. doi: 10.1021/ja905082c.
The first examples of Suzuki-Miyaura couplings of allylic ethers are reported. These can be done not only under very mild room-temperature conditions but also in water as the only medium. The process is made possible by micellar catalysis using the designer surfactant PTS.
报道了烯丙基醚的铃木-宫浦偶联反应的首个实例。这些反应不仅可以在非常温和的室温条件下进行,而且可以在仅以水为介质的情况下进行。该过程通过使用定制表面活性剂PTS的胶束催化得以实现。