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Rhodium-catalyzed cycloaddition of 1,6-enynes with 2-bromophenylboronic acids: synthesis of a multi-substituted dihydronaphthalene scaffold.

作者信息

Fang Xianjie, Li Chaolong, Tong Xiaofeng

机构信息

Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Shanghai 200237, China.

出版信息

Chem Commun (Camb). 2009 Sep 21(35):5311-3. doi: 10.1039/b910532h. Epub 2009 Jul 28.

DOI:10.1039/b910532h
PMID:19707656
Abstract

A formal [2 + 2 + 2] cycloaddition of a 1,6-enyne with 2-bromophenylboronic acid has been realized to construct a multi-substituted dihydronaphthalene scaffold, in which the direct reductive elimination mechanism of aryl-Rh(iii)-C(sp(3)) species has been established to form an aryl-C(sp(3)) bond.

摘要

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