Schuler Marie, Duvvuru Deepti, Retailleau Pascal, Betzer Jean-François, Marinetti Angela
Institut de Chimie des Substances Naturelles, CNRS, UPR 2301. 1, av. de la Terrasse-91198 Gif-sur-Yvette Cedex.
Org Lett. 2009 Oct 1;11(19):4406-9. doi: 10.1021/ol901758k.
Conjugated dienes, properly activated by electron-withdrawing groups on both ends, are shown to be suitable substrates for phosphine-promoted organocatalytic processes. Their reactions with imines, under phosphine catalysis, afford a new and efficient synthetic approach to functionalized 3-pyrrolines.
两端带有吸电子基团适当活化的共轭二烯，被证明是用于膦促进的有机催化过程的合适底物。在膦催化下，它们与亚胺的反应为功能化3-吡咯啉提供了一种新的高效合成方法。
