头状马钱子碱H的不对称全合成及结构修正

Asymmetric total synthesis and revised structure of cephalezomine H.

作者信息

Taniguchi Tsuyoshi, Yokoyama Shin'ichi, Ishibashi Hiroyuki

机构信息

School of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan.

出版信息

J Org Chem. 2009 Oct 2;74(19):7592-4. doi: 10.1021/jo901689a.

DOI:10.1021/jo901689a

PMID:19731926

Abstract

A revised structure of cephalezomine H, Cephalotaxus alkaloids, is presented. The originally assigned and revised structures of cephalezomine H were synthesized from the key intermediate for the synthesis of (-)-cephalotaxine.

摘要

本文给出了头状紫杉生物碱中头状紫堇明H的修订结构。头状紫堇明H最初指定的结构和修订后的结构是由（-）-头状紫杉碱合成的关键中间体合成的。