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[叶类蔬菜和瓶装水中高氯酸盐含量的监测]

[Surveillance of perchlorate level in leafy vegetables and bottled water].

作者信息

Takatsuki Satoshi, Watanabe Takahiro, Sakai Takatoshi, Matsuda Rieko, Maitani Tamio

机构信息

National Institute of Health Sciences, Tokyo, Japan.

出版信息

Shokuhin Eiseigaku Zasshi. 2009 Aug;50(4):184-9. doi: 10.3358/shokueishi.50.184.

Abstract

Perchlorate (ClO(4)(-)) is both a naturally occurring and artificial compound, and it inhibits iodide uptake into the thyroid gland and disturbs thyroid function. It has been detected in many foods in the United States. In order to investigate perchlorate contamination in foods in Japan, perchlorate level in 82 leafy vegetable samples and 20 bottled mineral water samples was measured using a procedure based on the FDA's procedure, employing IC-MS/MS with (18)O(4)-labeled perchlorate as an internal standard. Among 82 leafy vegetable samples tested, perchlorate levels were under the LOQ (0.3 ng/g) in 3 samples and ranged from 0.3 ng/g to 29.7 ng/g in 79 samples. In 20 bottled water samples, perchlorate was under the LOQ (0.1 ng/mL) in 14 samples and ranged from 0.14 ng/mL to 0.35 ng/mL in 6 samples.

摘要

高氯酸盐(ClO₄⁻)是一种既天然存在又有人工合成的化合物,它会抑制碘化物摄入甲状腺并干扰甲状腺功能。在美国的许多食品中都检测到了它。为了调查日本食品中的高氯酸盐污染情况,采用基于美国食品药品监督管理局(FDA)方法的程序,以¹⁸O₄标记的高氯酸盐作为内标,使用离子色谱-串联质谱法(IC-MS/MS)对82份叶菜类蔬菜样品和20份瓶装矿泉水样品中的高氯酸盐含量进行了测定。在测试的82份叶菜类蔬菜样品中,3份样品的高氯酸盐含量低于定量限(0.3纳克/克),79份样品的含量在0.3纳克/克至29.7纳克/克之间。在20份瓶装水样品中,14份样品的高氯酸盐含量低于定量限(0.1纳克/毫升),6份样品的含量在0.14纳克/毫升至0.35纳克/毫升之间。

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