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北美和欧洲地表水系统中双酚A的暴露分析。

Exposure analysis of bisphenol A in surface water systems in North America and Europe.

作者信息

Klecka Gary M, Staples Charles A, Clark Kathryn E, Van der Hoeven Nelly, Thomas David E, Hentges Steven G

机构信息

The Dow Chemical Company, Midland, Michigan 48674, USA.

出版信息

Environ Sci Technol. 2009 Aug 15;43(16):6145-50. doi: 10.1021/es900598e.

Abstract

This study was conducted to develop a statistical understanding of exposures to bisphenol A (BPA) in aquatic environments in North America and Europe. Concentrations of BPA have been reported by 89 investigations published between 1997 and 2007. On the basis of an analysis of weighted observations (n = 1068 and 848 for North America and Europe, respectively), BPA was reported at concentrations above the detection limit in 20-51% of freshwater samples. Median BPA concentrations for fresh surface waters for North America and Europe were 0.081 and 0.01 microg/L, respectively, while 95th percentiles were 0.47 and 0.35 microg/L, respectively. In contrast to fresh surface waters, only limited data are available for sediments and less for marine ecosystems. For freshwater sediments in North America (n = 71), the median and 90th percentile concentration (the 95th percentile was not calculable) were 0.6 and 3.4 ng/ g-dw, respectively, while the median and 95th percentile concentration in Europe (n = 249) were 16 and 256 ng/g-dw, respectively. To assess the potential ecological significance, we compared exposure concentrations with available regulatory criteria. The results suggest the frequency of locations in which concentrations are likely to cause adverse effects on aquatic ecosystems is low, with the exception of sediments collected from some highly urbanized and industrial locations.

摘要

本研究旨在对北美和欧洲水生环境中双酚A(BPA)的暴露情况进行统计学理解。1997年至2007年间发表的89项调查报道了双酚A的浓度。基于加权观测值分析(北美和欧洲分别为n = 1068和848),在20% - 51%的淡水样本中报告的双酚A浓度高于检测限。北美和欧洲新鲜地表水的双酚A中位数浓度分别为0.081和0.01微克/升,而第95百分位数分别为0.47和0.35微克/升。与新鲜地表水形成对比的是,沉积物的数据有限,海洋生态系统的数据更少。对于北美淡水沉积物(n = 71),中位数浓度和第90百分位数浓度(第95百分位数无法计算)分别为0.6和3.4纳克/克干重,而欧洲(n = 249)的中位数浓度和第95百分位数浓度分别为16和256纳克/克干重。为评估潜在的生态意义,我们将暴露浓度与现有的监管标准进行了比较。结果表明,除了从一些高度城市化和工业化地区采集的沉积物外,浓度可能对水生生态系统造成不利影响的地点频率较低。

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