三联苯冠醚：一类新的受体家族，其含有醚类冠层，可将钾阳离子导向苯环平台以形成阳离子-π相互作用。
Terphenyl crowns: a new family of receptors containing ethereal canopies that direct potassium cation onto benzenoid platforms for cation-pi interactions.
作者信息
Shukla Ruchi, Lindeman Sergey V, Rathore Rajendra
机构信息
Department of Chemistry, Marquette University, P. O. Box 1881, Milwaukee, Wisconsin 53201, USA.
出版信息
Chem Commun (Camb). 2009 Oct 7(37):5600-2. doi: 10.1039/b912796h. Epub 2009 Aug 20.
DOI:10.1039/b912796h
PMID:19753370
Abstract
We have synthesized three simple and versatile terphenyl crowns (TC) receptors containing ethereal canopies that direct a potassium cation for efficient cation-pi interactions as established by 1H NMR spectroscopy and by isolation and X-ray crystallography of their K+ salts.
摘要
我们合成了三种简单且通用的三联苯冠醚（TC）受体，其含有醚类冠层，通过1H NMR光谱以及其钾盐的分离和X射线晶体学确定，该冠层可引导钾阳离子进行有效的阳离子-π相互作用。
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