含有 C2h 对称三联苯二羧酸酯链接剂的 DABCO 功能化金属有机骨架。
DABCO-functionalized metal-organic framework bearing a C2h-symmetric terphenyl dicarboxylate linker.
机构信息
Department of Chemistry and Protein Research Center for Bio-Industry, Hankuk University of Foreign Studies, Yongin, 449-791, Korea.
出版信息
Dalton Trans. 2010 Jun 28;39(24):5608-10. doi: 10.1039/c0dt00392a. Epub 2010 May 24.
PMID:20498861
Abstract
A Zn-MOF assembled from a new C(2h)-symmetric terphenyl dicarboxylate and DABCO was prepared and characterized by X-ray crystallography and gas sorption analysis: a preferential sorption of CO(2) over N(2) and H(2) was observed with an exceptionally high CO(2) adsorption enthalpy.
摘要
一种由新型 C(2h)-对称三联苯二羧酸和 DABCO 组装的 Zn-MOF 通过 X 射线晶体学和气体吸附分析进行了制备和表征：观察到 CO(2)对 N(2)和 H(2)的优先吸附，具有异常高的 CO(2)吸附焓。
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