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葫芦岛市土壤和蔬菜中重金属污染的空间变异

[Spatial variation of heavy metals contamination in the soil and vegetables of Huludao City].

作者信息

Zheng Na, Wang Qi-Chao, Liu Jing-Shuang, Wang Yang, Zhang Zhong-Sheng

机构信息

Key Laboratory of Wetland Ecology and Environment, Northeast Institute of Geography and Agroecology, Chinese Academy of Sciences, Changchun 130012, China.

出版信息

Huan Jing Ke Xue. 2009 Jul 15;30(7):2071-6.

Abstract

Hg, Pb, Cd, Zn, and Cu concentrations in the soil, vegetables and crop of Huludao city were investigated. The Hg, Pb, Cd, Zn, and Cu concentrations in soils of the smelting areas are 1.422, 443.1, 60.94, 4084, and 247.8 mg x kg(-1), thus 6.092, 3195, 341.7, 35 157, and 1 557 mg x kg(-1) for the maximal concentrations, respectively. Spatial distribution maps of heavy metals concentrations in top soils in Huludao City were separately laid out by using Kriging. Heavy metals spatial distribution patterns in soils show that Ph, Cd, Zn, Cu emissions from Huludao Zinc Plant are the main pollution sources of heavy metals to the top soils in Huludao City, but Hg emission from Huludao Zinc Plant and chlor-alkali industry is the main pollution source of mercury to the top soils. Heavy metals concentrations in top soils decrease exponentially with distance from the zinc smelting area. Except Hg, the exponential equation could be better to fit the variety forother heavy metals. Heavy metals in vegetable and crop cultivated around Huludao Zinc Plant are higher than from markets, suggests that heavy metals affect the local soil and crops seriously.

摘要

对葫芦岛市土壤、蔬菜和农作物中的汞、铅、镉、锌和铜含量进行了调查。冶炼区土壤中汞、铅、镉、锌和铜的含量分别为1.422、443.1、60.94、4084和247.8毫克/千克,最大含量分别为6.092、3195、341.7、35157和1557毫克/千克。利用克里金法分别绘制了葫芦岛市表层土壤重金属含量空间分布图。土壤中重金属空间分布格局表明,葫芦岛锌厂的铅、镉、锌、铜排放是葫芦岛市表层土壤重金属的主要污染源,但葫芦岛锌厂和氯碱行业的汞排放是表层土壤汞的主要污染源。表层土壤中重金属含量随距锌冶炼区距离的增加呈指数下降。除汞外,指数方程能更好地拟合其他重金属的变化。葫芦岛锌厂周边种植的蔬菜和农作物中的重金属含量高于市场上的,表明重金属对当地土壤和农作物影响严重。

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