三（2,4,6-三甲氧基苯基）膦（TTMPP）：用于醛和酮的氰基硅烷化及氰基羰基化反应的高效催化剂。
Tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP): efficient catalysts for the cyanosilylation and cyanocarbonation of aldehydes and ketones.
作者信息
Matsukawa Satoru, Sekine Izumi, Iitsuka Ayumi
机构信息
Department of Science Education, Faculty of Education, Ibaraki University, Ibaraki, 310-8512 Japan.
出版信息
Molecules. 2009 Sep 2;14(9):3353-9. doi: 10.3390/molecules14093353.
Abstract
A variety of aldehydes and ketones were transformed to their corresponding cyanohydrin silyl ethers in good to excellent yields in the presence of 1-5 mol% of tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP). Cyanohydrin carbonates were also readily prepared using 5-10 mol% of TTMPP as an organocatalyst.
摘要
在1-5摩尔%的三（2,4,6-三甲氧基苯基）膦（TTMPP）存在下，多种醛和酮被转化为相应的氰醇硅醚，产率良好至优异。使用5-10摩尔%的TTMPP作为有机催化剂也能很容易地制备氰醇碳酸酯。
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