Department of Chemistry, Georgetown University, Box 571227, Washington, DC 20057-1227, USA.
Chem Commun (Camb). 2009 Oct 21(39):5847-9. doi: 10.1039/b911643e. Epub 2009 Sep 8.
Two coordinate copper(I) thiolates IPrCu-SR undergo rapid, reversible transnitrosation with S-nitrosothiols RSNOs without catalyzing the loss of NO(gas) from these biological carriers of NO.
两个配位的一价铜硫醇配合物 IPrCu-SR 可与 S-亚硝酰硫醇 RSNO 发生快速、可逆的转亚硝基反应,而不会催化这些一氧化氮(气体)生物载体中 NO 的损失。