Japan Synchrotron Radiation Research Institute (JASRI/SPring-8), Sayo, Hyogo, Japan.
J Synchrotron Radiat. 2009 Nov;16(Pt 6):730-6. doi: 10.1107/S0909049509034700. Epub 2009 Sep 15.
An X-ray magnetic circular dichroism experiment under multiple extreme conditions, 2 <or= T <or= 300 K, H <or= 10 T and P <or= 50 GPa, has been achieved at SPring-8 BL39XU. A combination of the high-brilliant X-ray beam and a helicity-controlled technique enabled the dichroic signal to be recorded with high accuracy. The performance is shown by the outcome of pressure-induced ferromagnetism in Mn(3)GaC and the pressure-suppressed Co moment in ErCo(2). Two technical developments, a tiny diamond anvil cell inserted into a superconducting magnet and in situ pressure calibration using 90 degrees Bragg diffraction from a NaCl marker, are also presented. X-ray magnetic spectroscopy under multiple extreme conditions is now opening a new approach to materials science.
在 SPring-8 BL39XU,实现了在多种极端条件下(2 <= T <= 300 K、H <= 10 T 和 P <= 50 GPa)的 X 射线磁圆二色性实验。高亮度 X 射线束和螺旋控制技术的结合,使我们能够以高精度记录二色性信号。该实验通过 Mn(3)GaC 的压力诱导铁磁性和 ErCo(2)中的 Co 磁矩的压力抑制这两个结果得到了验证。本文还介绍了两项技术进展,即插入超导磁体的微小金刚石压腔和使用 NaCl 标记物的 90 度布拉格衍射进行原位压力校准。多极端条件下的 X 射线磁光谱学现在为材料科学开辟了一条新途径。