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用于汞离子(Hg2+)的小分子荧光化学传感器。

Small-molecule fluorescent chemosensors for Hg2+ ion.

作者信息

Zhang Jun Feng, Kim Jong Seung

机构信息

Department of Chemistry, Korea University, Seoul 136-701, Korea.

出版信息

Anal Sci. 2009 Nov;25(11):1271-81. doi: 10.2116/analsci.25.1271.

Abstract

Fluorometric determination techniques for mercury (Hg2+) assays have been very popular in recent years. This review focuses mainly on advances in the field of fluorescent sensors, concerning the detection of Hg2+ ion, that have been developed over the last few years. Based on a difference among the bearing functional fluorophores, these works are divided into two major sections. In the first section, rhodamine-derived Hg2+ ion sensors have been reviewed according to the essential mechanisms that work together with the spirolactam ring opening reaction. Various fluorescence Hg2+ ion sensors based on other functional fluorophores are discussed in the second section, divided by their recognition mechanisms that used for the signal responses.

摘要

近年来,用于汞(Hg2+)检测的荧光测定技术非常流行。本综述主要关注过去几年中在荧光传感器领域取得的进展,这些进展涉及Hg2+离子的检测。基于所承载的功能性荧光团之间的差异,这些研究工作分为两个主要部分。在第一部分中,根据与螺内酰胺开环反应协同作用的基本机制,对罗丹明衍生的Hg2+离子传感器进行了综述。第二部分讨论了基于其他功能性荧光团的各种荧光Hg2+离子传感器,根据它们用于信号响应的识别机制进行划分。

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