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膦基-和磷酰基-2H-氮丙啶、亚硝烯和偶氮烯的加成和环加成反应。

Addition and cycloaddition reactions of phosphinyl- and phosphonyl-2H-azirines, nitrosoalkenes and azoalkenes.

机构信息

CIQA, Faculdade de Ciências e Tecnologia, Universidade do Algarve, Campus de Gambelas, 8005-137 Faro, Portugal.

出版信息

Molecules. 2009 Oct 13;14(10):4098-119. doi: 10.3390/molecules14104098.

DOI:10.3390/molecules14104098
PMID:19924050
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6254798/
Abstract

An overview of the use of 2H-azirines, conjugated nitrosoalkenes and conjugated azoalkenes bearing phosphorus substituents in addition and cycloaddition reactions is presented, focused on strategies for the synthesis of aminophosphonate and aminophosphine oxide derivatives.

摘要

介绍了含磷取代基的 2H-氮杂环丁二烯、共轭亚硝基烯和共轭偶氮烯在加成和环加成反应中的应用概述，重点介绍了合成氨基膦酸酯和氨基氧化膦衍生物的策略。

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