铜催化的 N-对甲苯磺酰基氮丙啶和腙在有氧条件下的亲核开环/分子内氧化酰胺化反应。
Copper-catalyzed tandem nucleophilic ring-opening/intramolecular oxidative amidation of N-tosylaziridines and hydrazones under aerobic conditions.
机构信息
Department of Chemistry, Zhejiang University, Hangzhou 310027, People's Republic of China.
出版信息
Org Lett. 2009 Dec 17;11(24):5678-81. doi: 10.1021/ol902376w.
PMID:19924904
Abstract
A novel and efficient copper-catalyzed tandem reaction of N-tosylaziridines and hydrazones under aerobic conditions to afford the functionalized tetrahydrotriazines is described. The process involves a nucleophilic ring-opening and an intramolecular oxidative amidation.
摘要
一种新型、高效的铜催化 N-对甲苯磺酰基氮丙啶和腙在有氧条件下的串联反应，以提供功能化的四氢三嗪。该过程涉及亲核开环和分子内氧化酰胺化。
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