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增强聚丙烯复合材料:化学成分和粒径的影响。

Reinforced polypropylene composites: effects of chemical compositions and particle size.

机构信息

Department of Chemical Industries, Iranian Research Organization for Science and Technology (IROST), Tehran, Iran.

出版信息

Bioresour Technol. 2010 Apr;101(7):2515-9. doi: 10.1016/j.biortech.2009.11.022. Epub 2009 Nov 30.

Abstract

In this work, the effects of wood species, particle sizes and hot-water treatment on some physical and mechanical properties of wood-plastic composites were studied. Composites of thermoplastic reinforced with oak (Quercus castaneifolia) and pine (Pinus eldarica) wood were prepared. Polypropylene (PP) and maleic anhydride grafted polypropylene (MAPP) were used as the polymer matrix and coupling agent, respectively. The results showed that pine fiber had significant effect on the mechanical properties considered in this study. This effect is explained by the higher fiber length and aspect ratio of pine compared to the oak fiber. The hot-water treated (extractive-free) samples, in both wood species, improved the tensile, flexural and impact properties, but increased the water absorption for 24h. This work clearly showed that lignocellulosic materials in both forms of fiber and flour could be effectively used as reinforcing elements in PP matrix. Furthermore, extractives have marked effects on the mechanical and physical properties.

摘要

在这项工作中,研究了木材种类、粒径和热水处理对木塑复合材料某些物理和机械性能的影响。制备了以阔叶橡木(Quercus castaneifolia)和马尾松(Pinus eldarica)木材为增强体的热塑性复合材料。分别使用聚丙烯(PP)和马来酸酐接枝聚丙烯(MAPP)作为聚合物基体和偶联剂。结果表明,在本研究中考虑的力学性能方面,松木纤维具有显著的影响。这一效果可以通过与橡木纤维相比,松木纤维具有更长的纤维长度和更高的长径比来解释。与未处理(无抽提物)的样品相比,两种木材的热水处理样品均提高了拉伸、弯曲和冲击性能,但 24 小时吸水率增加。这项工作清楚地表明,纤维和木粉形式的木质纤维素材料可以有效地用作 PP 基体的增强元素。此外,抽提物对力学和物理性能有显著影响。

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