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Silylene oxonium ylides: di-tert-butylsilylene insertion into C-O bonds.
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Vinyl-, propargyl-, and allenylsilicon reagents in asymmetric synthesis: a relatively untapped resource of environmentally benign reagents.
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Amination of allylic alcohols in water at room temperature.
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Cross-coupling of aromatic bromides with allylic silanolate salts.
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Recent progress in Lewis base activation and control of stereoselectivity in the additions of trimethylsilyl nucleophiles.
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Catalytic asymmetric synthesis of allylsilanes through rhodium/chiral diene-catalyzed 1,4-addition of alkenyl[2-(hydroxymethyl)phenyl]dimethylsilanes.
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