Department of Chemistry, Graduate School of Engineering Science, Osaka University, Machikaneyama, Toyonaka, Osaka 560-8531, Japan.
Org Lett. 2010 Jan 1;12(1):32-5. doi: 10.1021/ol902393p.
Various olefins can be hydrogenated quantitatively with neutral flavin 2 catalysts in the presence of 1-2 equiv of hydrazine under 1 atm of O(2). Vitamin B(2) derivative 2g acts as a highly efficient and robust catalyst for the present environmentally benign process producing water and nitrogen gas as the only waste products.
各种烯烃可以在中性黄素 2 催化剂存在下,在 1 大气压 O(2)下,使用 1-2 当量的联氨定量加氢。维生素 B(2)衍生物 2g 是一种高效、稳定的催化剂,适用于目前这种环境友好的过程,产物只有水和氮气。