Environmental Engineering Department, CEIT and Tecnun (University of Navarra), Manuel Lardizabal 15, 20018, San Sebastian, Spain.
Water Sci Technol. 2009;60(12):3233-41. doi: 10.2166/wst.2009.612.
This paper presents how, in a calibration process, different assumptions regarding the standard Mixed-Culture Biofilms (MCB) model were able to match the average results at a continuous Johannesburg pilot plant (comprising two aerobic reactors, AE1 and AE2), but failed to match the batch test results of either the rate of endogenous carbonaceous oxygen uptake (OUR) or the rate of nitrate production (NPR). Under the first assumption, where attachment and diffusion of particulate components were not used, the OUR in the biofilm of the first aerobic reactor (AE1) was too low due to the absence of slowly biodegradable COD (X(S)) attachment flux. In a second assumption, where high diffusion and attachment coefficients were used, the NPR in the biofilm of the AE1 reactor exceeded the experimental value due to the high attachment flux used for nitrifiers (X(A)) and the low competition for space from X(S) and heterotrophic bacteria (X(H)). The only way to match all the experimental results was through the use of a higher attachment coefficient for X(S) in the first reactor (AE1), but this was considered unreasonable. Hence, an extended model was developed where a colloidal state, which interacts at the same time with the flocs and the biofilm through attachment-detachment processes, is distinguished. This model allowed the experimental results to be matched, but using the same value for the attachment coefficients of all particulate components.
本文介绍了在标定过程中,不同的标准混合培养生物膜(MCB)模型假设如何能够匹配约翰内斯堡中试工厂(由两个好氧反应器 AE1 和 AE2 组成)的平均结果,但无法匹配批式试验中内源碳氧摄取率(OUR)或硝酸盐生成率(NPR)的结果。在第一个假设中,由于没有使用颗粒成分的附着和扩散,第一个好氧反应器(AE1)生物膜中的 OUR 过低,因为缺少缓慢可生物降解 COD(X(S))的附着通量。在第二个假设中,由于使用了高扩散和附着系数,AE1 反应器生物膜中的 NPR 超过了实验值,因为用于硝化菌(X(A))的附着通量很高,并且 X(S)和异养菌(X(H))对空间的竞争较低。唯一能够匹配所有实验结果的方法是在第一个反应器(AE1)中使用更高的 X(S)附着系数,但这被认为是不合理的。因此,开发了一个扩展模型,其中区分了胶体状态,胶体状态通过附着-脱附过程同时与絮体和生物膜相互作用。该模型允许匹配实验结果,但使用所有颗粒成分的相同附着系数。