Department of Engineering, University of Liverpool, Liverpool, United Kingdom.
J Am Soc Mass Spectrom. 2010 Feb;21(2):317-22. doi: 10.1016/j.jasms.2009.10.020. Epub 2009 Nov 5.
This article presents the design, construction, and test results of a linear ion trap, fabricated using digital light processing (DLP), which is a low-cost 3D layer-based manufacturing technique. The ion trap was incorporated into a portable mass spectrometer system and experimental mass spectrum was obtained for methamphetamine (m/z 182), cocaine (m/z 304), and rhodamine B (m/z 443), with a maximum observed resolution (FWHM) of 260. For rhodamine B, tandem MS capability is also demonstrated. The mass range (and resolution at higher m/z) of the instrument is also demonstrated by spectrum obtained from Ultramark (m/z 1621). The spectra obtained for the DLP trap occur at a considerably lower rf voltage than a rectilinear ion trap of similar size, which is a consequence of the hyperbolic electrode geometry and, hence, smaller r(0) in the DLP case. High mass range with low voltage operation is especially important with regard to 'in the field' applications requiring low power consumption for extended periods of operation.
本文介绍了一种使用数字光处理(DLP)制造的线性离子阱的设计、构建和测试结果,DLP 是一种低成本的 3D 层状制造技术。该离子阱被集成到一个便携式质谱仪系统中,并获得了甲基苯丙胺(m/z 182)、可卡因(m/z 304)和罗丹明 B(m/z 443)的实验质谱,最大观察分辨率(FWHM)为 260。对于罗丹明 B,还展示了串联 MS 能力。通过从 Ultramark(m/z 1621)获得的光谱,还展示了仪器的质量范围(以及更高 m/z 处的分辨率)。与类似尺寸的直线离子阱相比,DLP 阱获得的光谱所需的射频电压要低得多,这是双曲线电极几何形状的结果,因此在 DLP 情况下 r(0) 较小。对于需要低功耗和长时间运行的“现场”应用,高质量范围和低电压操作尤其重要。