Wang Chao, Xue An, Zhao Hua-zhang, Zhang Bao-gang, Ni Jin-ren
Key Laboratory of Water and Sediment Sciences, Ministry of Education, Department of Environmental Engineering, Peking University, Beijing 100871, China.
Huan Jing Ke Xue. 2009 Oct 15;30(10):3093-8.
The possibility of electricity generation in a single chamber microbial fuel cell fed with Dioscorea zingiberensis C. H. Wright wastewater was demonstrated, and the effects of COD and SO4(2-) concentration on MFC performance were investigated. Under the same conductivity and COD concentration, the power density generated from wastewater equaled to 80.3% of that from glucose. At low COD concentration, the electricity generation increased with increasing COD loading rates, and the maximum power density was 322 mW/m2; while the COD concentration was enhanced over 2766 mg/L, the stable times for electricity generation was reduced and the MFC could not recover to previous performance as refueling. That indicates high COD loading rates would inhibit microbial activity. The COD removal rates varied from 68.2% to 84.8%, and it decreased when COD concentration climbed up. The power density was enhanced with SO4(2-) concentration increasing up to 7716 mg/L (Conductivity > 8.19 mS/cm) after which no further improvements in power density were observed. The maximum power density of the wastewater containing SO4(2-) was lower by 14.5% on average than that of the wastewater which removed SO4(2-). And its coulombic efficiencies declined substantially as SO4(2-) concentration increasing, which imply that the SO4(2-) is deoxidized as the electron acceptor, which takes the MFC efficiency down.
研究了以黄独废水为燃料的单室微生物燃料电池发电的可能性,并考察了化学需氧量(COD)和硫酸根离子(SO4(2-))浓度对微生物燃料电池性能的影响。在相同电导率和COD浓度下,废水产生的功率密度相当于葡萄糖产生功率密度的80.3%。在低COD浓度下,发电量随COD负荷率的增加而增加,最大功率密度为322 mW/m2;当COD浓度超过2766 mg/L时,发电稳定时间缩短,且微生物燃料电池在重新加燃料后无法恢复到之前的性能。这表明高COD负荷率会抑制微生物活性。COD去除率在68.2%至84.8%之间变化,且随着COD浓度升高而降低。随着SO4(2-)浓度增加至7716 mg/L(电导率>8.19 mS/cm),功率密度增强,之后未观察到功率密度进一步提高。含SO4(2-)废水的最大功率密度平均比去除SO4(2-)的废水低14.5%。并且随着SO4(2-)浓度增加,其库仑效率大幅下降,这意味着SO4(2-)作为电子受体被还原,从而降低了微生物燃料电池的效率。