Department of Chemistry & Environmental Biotechnology National Core Research Center, Research Institute of Natural Sciences, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University, Jinju 660-701, Korea.
J Org Chem. 2010 Jan 15;75(2):484-6. doi: 10.1021/jo902356e.
Conversion of oximes to the carbonyl compounds has been demonstrated with use of 2-nitro-4,5-dichloropyridazin-3(2H)-one (2) under microwave irradiated conditions. Fourteen aliphatic and aromatic oximes converted to their corresponding aldehydes and ketones in good to excellent yields. It is noteworthy that the reaction is conducted under neutral, mild, and eco-friendly condition.
在微波辐射条件下，使用 2-硝基-4,5-二氯哒嗪-3(2H)-酮（2）已证明可以将肟转化为羰基化合物。14 种脂肪族和芳香族肟以良好至优异的产率转化为相应的醛和酮。值得注意的是，该反应在中性、温和且环保的条件下进行。
