Das Debadutta, Mohapatra Ranjan K, Parhi Pankaj K, Sarangi Ashish K, Sahu Raghaba, Barik Soumya R
Department of Chemistry, Sukanti Degree College, Subarnapur, Odisha 767017, India.
Department of Chemistry, Government College of Engineering, Keonjhar, Odisha 758002, India.
ACS Omega. 2020 Mar 25;5(13):7716-7721. doi: 10.1021/acsomega.0c00774. eCollection 2020 Apr 7.
The synthesis of organic compounds using aqueous medium has become an indispensable tool for modern chemical synthesis strategies because of its ability to produce pure products with higher yield at ambient temperature. The conversion of oxime group into carbonyl group serves as a key step for several organic syntheses. This article describes the regeneration of carbonyl compounds from the oxime group present in various carbon skeletons using I and aqueous extract of under microwave radiation. A correlation has been established between the critical micellar concentration of saponin extracted from and the yield percentage of regenerated different carbonyl compounds. An effortless, competent, and environmentally compassionate protocol for the regeneration of carbonyl compound with a high percent of yield in the range 45-95% could be achieved.
使用水介质合成有机化合物已成为现代化学合成策略中不可或缺的工具，因为它能够在常温下以更高的产率生产纯产品。肟基转化为羰基是几种有机合成的关键步骤。本文描述了在微波辐射下，使用碘和[具体物质]的水提取物，从各种碳骨架中存在的肟基再生羰基化合物。已建立了从[具体植物]中提取的皂苷的临界胶束浓度与再生不同羰基化合物的产率百分比之间的相关性。可以实现一种轻松、高效且环境友好的方案，用于以45 - 95%的高产率再生羰基化合物。
