Department of Chemistry and Biochemistry and Center for Nano and Molecular Science and Technology, The University of Texas at Austin, 1 University Station, A5300, Austin, Texas 78712-0165, USA.
J Am Chem Soc. 2009 Dec 30;131(51):18196-7. doi: 10.1021/ja906773g.
Electropolymerization of bithiophene-substituted cadmium(II) Schiff base complexes forms thin conducting metallopolymer films with metal centers distributed throughout. The metal centers act as seed points for direct growth of CdS nanoparticles within the polymer matrix under mild reaction conditions. This synthetic approach offers control over both the size and distribution density of the nanoparticles formed within the polymer film. The resulting hybrid materials hold promise for a variety of organic electronic and optoelectronic applications.
联噻吩取代的镉(II)希夫碱配合物的电聚合形成了具有金属中心分布在其中的薄导电金属聚合物膜。在温和的反应条件下，金属中心充当了在聚合物基质中直接生长 CdS 纳米粒子的晶种点。这种合成方法可以控制在聚合物膜中形成的纳米粒子的尺寸和分布密度。所得到的杂化材料有望应用于各种有机电子和光电应用。
