Department of Chemistry & Biochemistry and the Center for Nano and Molecular Science and Technology, The University of Texas at Austin, 1 University Station, A5300, Austin, TX 78712-0165, USA.
Chem Commun (Camb). 2010 Aug 7;46(29):5355-7. doi: 10.1039/c0cc00578a. Epub 2010 Jun 16.
Electropolymerization of novel gallium Schiff-base complexes results in conducting metallopolymers containing either coordinatively saturated or unsaturated gallium metal centers. Depending on the chemical coordination of the metal centers, the embedded metal ions can act as seed points for the direct growth of size-controlled gallium sulfide nanoparticles in a conducting polymer, yielding a hybrid electronic material.
新型镓希夫碱配合物的电化学聚合导致形成含有配位饱和或不饱和镓金属中心的导电金属聚合物。根据金属中心的化学配位情况，嵌入的金属离子可以作为在导电聚合物中直接生长尺寸可控的硫化镓纳米粒子的种子点，从而得到一种混合电子材料。
