一种高效、选择性且无需还原剂的铜催化剂，用于卤代化合物与活化烯烃的原子转移自由基加成反应。
An efficient, selective, and reducing agent-free copper catalyst for the atom-transfer radical addition of halo compounds to activated olefins.
机构信息
Laboratorio de Catálisis Homogénea, Departamento de Química y Ciencia de los Materiales, Unidad Asociada al CSIC, Campus de El Carmen, Universidad de Huelva, 21007-Huelva, Spain.
出版信息
Inorg Chem. 2010 Jan 18;49(2):642-5. doi: 10.1021/ic901942p.
PMID:20000619
Abstract
Efficient and selective ATRA reactions of CCl(4), CBr(4), TsCl (Ts = tosyl), or Cl(3)CCO(2)Et with activated olefins (styrene, methyl methacrylate, n-butyl methacrylate, tert-butyl methacrylate) using the Tp(tBu)Cu(NCMe) complex as a catalyst have been achieved in the absence of any reductant and with low catalyst loadings.
摘要
采用 Tp(tBu)Cu(NCMe) 配合物作为催化剂，在没有任何还原剂和低催化剂负载的情况下，实现了 CCl(4)、CBr(4)、TsCl (Ts = tosyl) 或 Cl(3)CCO(2)Et 与活化烯烃（苯乙烯、甲基丙烯酸甲酯、甲基丙烯酸正丁酯、甲基丙烯酸叔丁酯）的高效和选择性 ATRA 反应。
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