以RuIII配合物作为催化剂前体的高效原子转移自由基加成反应。
Highly efficient atom transfer radical addition reactions with a RuIII complex as a catalyst precursor.
作者信息
Quebatte Laurent, Thommes Katrin, Severin Kay
机构信息
Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), CH-1015 Lausanne, Switzerland.
出版信息
J Am Chem Soc. 2006 Jun 14;128(23):7440-1. doi: 10.1021/ja0617542.
PMID:16756288
Abstract
The combination of the air-stable RuIII complex [Cp*RuCl2(PPh3)] with AIBN can be used to catalyze the atom transfer radical addition reactions of polychlorinated compounds and of sulfonyl chlorides to olefins with unprecedented turnover numbers of up to 44 000.
摘要
空气稳定的RuIII配合物[Cp*RuCl2(PPh3)]与偶氮二异丁腈（AIBN）的组合可用于催化多氯化合物和磺酰氯与烯烃的原子转移自由基加成反应，其转换数高达44000，这是前所未有的。
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