Karlsruher Institut fur Technologie, Institut fur Nanotechnologie, Karlsruhe, Germany.
Nano Lett. 2010 Jan;10(1):187-94. doi: 10.1021/nl903262b.
Nanoporous Au-Pt alloys with pore- and ligament size down to few nanometers were fabricated by dealloying Ag-Au-Pt. Owing to the small structure size and large specific surface area, the surface stress and its variation give rise to significant stress and strain in the bulk of these materials. In fact, dilatometry experiments find electrochemical actuation with large reversible strain amplitude. The linear strain reaches approximately 1.3% and strain energy density is up to 6.0 MJ/m(3). The associated stresses may approach the elastic limit of the alloy.
通过脱合金化制备了具有几纳米以下孔和连接体尺寸的纳米多孔 Au-Pt 合金。由于结构尺寸小和比表面积大,表面应力及其变化导致这些材料的体相产生显著的应力和应变。实际上,膨胀计实验发现具有大的可逆应变幅度的电化学致动。线性应变达到约 1.3%,应变能密度高达 6.0MJ/m(3)。相关的应力可能接近合金的弹性极限。