Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, Polígono de La Coma s/n, E-46980 Paterna, Valencia, Spain.
Inorg Chem. 2010 Jan 18;49(2):377-9. doi: 10.1021/ic902217g.
Polyanion {Ce(H(2)O)(2)}(2)Mn(2)(B-alpha-GeW(9)O(34))(2) (1) constitutes the first example of a heterometallic 3d-4f cluster related to the Weakley-type dimeric structure, and it contains an unprecedented Ce(III)(2)Mn(III)(2)O(20) rhomblike moiety displaying dominant Ce(III)-Mn(III) ferromagnetic interactions.
多阴离子{Ce(H(2)O)(2)}(2)Mn(2)(B-alpha-GeW(9)O(34))(2) (1)构成了首例与 Weakley 型二聚结构相关的异金属 3d-4f 簇的例子，并且它包含了一个前所未有的 Ce(III)(2)Mn(III)(2)O(20)菱形状部分，显示出主导的 Ce(III)-Mn(III)铁磁相互作用。
