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带有螺芴结构单元的高荧光 BODIPY 染料。

Highly fluorescent BODIPY dyes modulated with spirofluorene moieties.

机构信息

Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.

出版信息

Org Lett. 2010 Jan 15;12(2):296-9. doi: 10.1021/ol902631d.

Abstract

A new type of structurally rigid BODIPY dye having spirofluorene moieties has been synthesized. These structurally constrained BODIPY dyes with spirofluorene moieties exhibit an intense bathochromic fluorescence. The solvent dependence of fluorescence ON/OFF switching of a BODIPY dye having an amino moiety was observed.

摘要

一种新型结构刚性的具有螺芴部分的 BODIPY 染料已经被合成。这些具有螺芴部分的结构受限的 BODIPY 染料表现出强烈的红移荧光。具有氨基部分的 BODIPY 染料的荧光 ON/OFF 开关的溶剂依赖性被观察到。

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