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多功能三嗪 - 硼二吡咯共轭物:合成策略、光物理见解及新兴应用。

Multifunctional -triazine-BODIPY conjugates: synthetic strategies, photophysical insights, and emerging applications.

作者信息

Nayak Laxmipriya, Acharya Subhadeep, Routray Supriya, Pattnaik Simran, Satapathy Rashmirekha

机构信息

Department of Chemistry, Ravenshaw University Cuttack-753003 Odisha India

出版信息

RSC Adv. 2025 Aug 8;15(34):27951-27994. doi: 10.1039/d5ra04624f. eCollection 2025 Aug 1.

Abstract

The integration of -triazine and BODIPY scaffolds has emerged as a versatile strategy for developing multifunctional conjugates with tailored photophysical and biological properties. This review provides a detailed overview of the different design principles, synthetic strategies, and applications of -triazine BODIPY conjugates in the last decade. Key photophysical parameters such as absorption maxima, fluorescence lifetimes, quantum yields, and singlet oxygen generation efficiencies are examined in the context of their structure-property relationships. The diverse applications of the conjugates are categorized into three primary domains such as biological application, including imaging and photodynamic therapy; sensing applications with discussions about mechanisms like PET, ICT, ESIPT and FRET; and advanced material applications, including their use as molecular rotors, liquid crystals, photocatalysts for CO reduction, and components in solar cells and optoelectronic devices. This work underscores the growing importance of -triazine-BODIPY conjugates as a modular platform for future innovations across materials science, analytical chemistry, and biomedical fields.

摘要

将三嗪和BODIPY支架整合已成为开发具有定制光物理和生物学特性的多功能共轭物的通用策略。本综述详细概述了过去十年中三嗪-BODIPY共轭物的不同设计原则、合成策略及应用。在其结构-性质关系的背景下,研究了诸如最大吸收波长、荧光寿命、量子产率和单线态氧生成效率等关键光物理参数。共轭物的多种应用被分为三个主要领域,如生物应用,包括成像和光动力疗法;传感应用,并讨论了PET、ICT、ESIPT和FRET等机制;以及先进材料应用,包括用作分子转子、液晶、用于CO还原的光催化剂以及太阳能电池和光电器件中的组件。这项工作强调了三嗪-BODIPY共轭物作为材料科学、分析化学和生物医学领域未来创新的模块化平台的重要性日益增加。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1526/12377070/c3a30fca45f7/d5ra04624f-s23.jpg

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