CSIRO Entomology, Canberra, ACT 2601, Australia.
Pest Manag Sci. 2010 Apr;66(4):417-24. doi: 10.1002/ps.1893.
Vapormate is a cylinderised non-flammable mixture of ethyl formate (16.7% by weight) and carbon dioxide (CO(2)) that has been developed as a rapid fumigant of stored grain. Four field trials were undertaken on wheat in 50 t farm silos to demonstrate the feasibility of dynamic application. To assess treatment efficacy, each trial tested mixed stages of Rhyzopertha dominica F. (>11,000), Tribolium castaneum (Herbst.) (>1500) and Sitophilus oryzae (L.) (>13,000) in mesh cages positioned through the centre of the grain bulk and on the grain surface. Ethyl formate and CO(2) concentrations were measured in the silo during fumigation and in ambient air outside the 6 m fumigation zone. Application rates of 420, 660 and 940 g m(-3) of ethyl formate/CO(2) formulation and exposure times of 24, 3 and 72 h, respectively, were examined using wheat of 10.4-11.7% moisture content and grain temperatures between 2 and 32 degrees C.
All life stages of R. dominica and T. castaneum were fully controlled under all conditions tested, and mortality of all life stages of S. oryzae was greater than 98%.
Dynamic application of vaporised ethyl formate and CO(2) to 50 t silos proved safe to operators and rapidly effective against stored-grain insects on cold to warm grain.
Vapormate 是一种圆柱状的不可燃混合物,由甲酸乙酯(重量的 16.7%)和二氧化碳(CO(2))组成,已被开发为一种快速熏蒸剂,用于储存谷物。在 50 吨农场筒仓中对小麦进行了四项田间试验,以证明动态应用的可行性。为了评估处理效果,每个试验都在通过粮堆中心和粮堆表面的网格笼中测试了混杂的玉米象(Rhyzopertha dominica F.)(>11,000 头)、赤拟谷盗(Tribolium castaneum)(>1500 头)和米象(Sitophilus oryzae)(>13,000 头)各阶段。在熏蒸过程中测量了筒仓中的甲酸乙酯和 CO(2)浓度,以及 6 米熏蒸区外的环境空气中的浓度。使用含水量为 10.4-11.7%、粮温在 2-32 摄氏度之间的小麦,分别检查了 420、660 和 940 g m(-3)的甲酸乙酯/CO(2)制剂的施药率和 24、3 和 72 h 的暴露时间。
在所测试的所有条件下,玉米象和赤拟谷盗的所有生活阶段都得到了完全控制,米象的所有生活阶段的死亡率都大于 98%。
在冷至暖的谷物上,将汽化的甲酸乙酯和 CO(2)动态应用于 50 吨筒仓对操作人员是安全的,并且对储存谷物昆虫的快速有效。