二烷基锌试剂对α，β-不饱和砜的催化不对称共轭加成。
Catalytic asymmetric conjugate addition of dialkylzinc reagents to alpha,beta-unsaturated sulfones.
机构信息
Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands.
出版信息
Org Biomol Chem. 2010 Jan 7;8(1):47-9. doi: 10.1039/b917269f. Epub 2009 Oct 1.
DOI:10.1039/b917269f
PMID:20024129
Abstract
An efficient method is reported for the highly enantioselective copper-catalyzed conjugate addition of dialkylzinc reagents to alpha,beta-unsaturated sulfones using a monodentate phosphoramidite ligand.
摘要
报道了一种使用单齿膦酰胺配体的高效、对映选择性铜催化二烷基锌试剂与α,β-不饱和砜的共轭加成反应的方法。
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