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1

Palladium-catalyzed [3C + 2C + 2C] cycloaddition of enynylidenecyclopropanes: efficient construction of fused 5-7-5 tricyclic systems.钯催化烯炔亚甲基环丙烷的 [3C + 2C + 2C] 环加成反应：高效构建稠合的 5-7-5 三环体系。

Chem Commun (Camb). 2010 Jan 14;46(2):270-2. doi: 10.1039/b919258a. Epub 2009 Nov 27.

2

Rhodium-catalyzed intramolecular [3+2+2] cycloadditions between alkylidenecyclopropanes, alkynes, and alkenes.铑催化的亚烷基环丙烷、炔烃和烯烃之间的分子内[3+2+2]环加成反应。

Chemistry. 2014 Aug 11;20(33):10255-9. doi: 10.1002/chem.201402473. Epub 2014 Jul 17.

3

Cobalt(I)-Catalyzed (3 + 2 + 2) Cycloaddition between Alkylidenecyclopropanes, Alkynes, and Alkenes.钴（I）催化的亚烷基环丙烷、炔烃和烯烃之间的（3 + 2 + 2）环加成反应

Org Lett. 2023 Nov 24;25(46):8372-8376. doi: 10.1021/acs.orglett.3c03511. Epub 2023 Nov 10.

4

Gold-catalyzed [4C+2C] cycloadditions of allenedienes, including an enantioselective version with new phosphoramidite-based catalysts: mechanistic aspects of the divergence between [4C+3C] and [4C+2C] pathways.金催化的联烯二烯[4C+2C]环加成反应，包括具有新型手性磷酰胺配体催化剂的对映选择性版本：[4C+3C]和[4C+2C]途径分歧的机理方面。

J Am Chem Soc. 2009 Sep 16;131(36):13020-30. doi: 10.1021/ja905415r.

5

Palladium-catalyzed highly regioselective [3 + 2] cycloaddition reactions of alkylidenecyclopropa[b]naphthalenes with alkenes or alkynes: an efficient synthesis of 1(3)-alkylidene-2,3-dihydro-1H-benzo[f]indenes and 1-alkylidene-1H-benzo[f]indenes.钯催化亚烷基环丙基[b]萘与烯烃或炔烃的高度区域选择性[3 + 2]环加成反应：1(3)-亚烷基-2,3-二氢-1H-苯并[f]茚和1-亚烷基-1H-苯并[f]茚的高效合成

Org Lett. 2008 Dec 18;10(24):5537-40. doi: 10.1021/ol8023083.

6

Ligand-induced acceleration of the intramolecular [3 + 2] cycloaddition between alkynes and alkylidenecyclopropanes.配体诱导的炔烃与亚烷基环丙烷之间分子内[3 + 2]环加成反应的加速。

Org Lett. 2005 Dec 8;7(25):5693-6. doi: 10.1021/ol0524095.

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Synthesis of tricyclic fused 3-aminopyridines through intramolecular Co(I)-catalyzed [2+2+2] cycloaddition between ynamides, nitriles, and alkynes.通过分子内钴（I）催化的烯酰胺、腈和炔烃之间的[2+2+2]环加成反应合成三环稠合的3-氨基吡啶。

Chemistry. 2009;15(9):2129-39. doi: 10.1002/chem.200802301.

8

Synthesis of 5-azaindolizine derivatives by the palladium-catalyzed intermolecular formal [3+2] cycloaddition of alkylidenecyclopropanes with 1,2-diazines.通过钯催化亚烷基环丙烷与1,2 - 二嗪的分子间形式[3 + 2]环加成反应合成5 - 氮杂吲哚嗪衍生物

J Org Chem. 2004 Apr 30;69(9):3202-4. doi: 10.1021/jo035810i.

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Palladium-catalyzed [2 + 2 + 2] cocyclotrimerization of benzynes with bicyclic alkenes: an efficient route to anellated 9,10-dihydrophenanthrene derivatives and polyaromatic compounds.钯催化苯炔与双环烯烃的[2 + 2 + 2]共环三聚反应：合成稠合9,10-二氢菲衍生物和多环芳烃化合物的有效途径。

J Org Chem. 2004 Nov 26;69(24):8445-50. doi: 10.1021/jo048702k.

10

Palladium(0)-catalyzed tandem cyclization of allenenes: direct construction of tricyclic heterocycles through aromatic C--H activation.钯（0）催化的丙二烯串联环化反应：通过芳香碳-氢键活化直接构建三环杂环化合物

Chemistry. 2005 Jun 6;11(12):3728-41. doi: 10.1002/chem.200500050.

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钯催化烯炔亚甲基环丙烷的 [3C + 2C + 2C] 环加成反应：高效构建稠合的 5-7-5 三环体系。

Palladium-catalyzed [3C + 2C + 2C] cycloaddition of enynylidenecyclopropanes: efficient construction of fused 5-7-5 tricyclic systems.

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