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分子碘--一种用于α,β-不饱和环状化合物氧化芳构化反应的简便试剂。

Molecular iodine--an expedient reagent for oxidative aromatization reactions of alpha,beta-unsaturated cyclic compounds.

机构信息

Department of Chemistry, College of Science, Engineering and Technology, University of South Africa, P.O. Box 392, Pretoria 0003, South Africa.

出版信息

Molecules. 2009 Dec 16;14(12):5308-22. doi: 10.3390/molecules14125308.

DOI:10.3390/molecules14125308
PMID:20032894
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6254800/
Abstract

Prompted by the scant attention paid by published literature reviews to the applications of molecular iodine in oxidative aromatization reactions, we decided to review methods developed to-date involving iodine as an oxidant to promote aromatization of alpha,beta-unsaturated cyclic compounds.

摘要

由于已发表的文献综述很少关注分子碘在氧化芳构化反应中的应用,我们决定对迄今为止涉及碘作为氧化剂促进α,β-不饱和环状化合物芳构化的方法进行综述。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/8643e3c9feb8/molecules-14-05308-sch017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/eee58328c52f/molecules-14-05308-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/792da8e8fa16/molecules-14-05308-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/5941700ba2e8/molecules-14-05308-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/efbc9632db98/molecules-14-05308-sch002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/2c95ae76c014/molecules-14-05308-sch003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/5e05d6d7cae6/molecules-14-05308-sch004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/c26712cd1f05/molecules-14-05308-sch005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/2fc27710cbd8/molecules-14-05308-sch006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/ae79a0c83567/molecules-14-05308-sch007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/7fb198699cac/molecules-14-05308-sch008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/7e608554ce7a/molecules-14-05308-sch009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/bd35d2e1daf5/molecules-14-05308-sch010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/41776a39e7ca/molecules-14-05308-sch011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/1c70c2ca32fb/molecules-14-05308-sch012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/637ad0773efa/molecules-14-05308-sch013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/e9cf2d7ca69d/molecules-14-05308-sch014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/54a293b303f9/molecules-14-05308-sch015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/548214c61f44/molecules-14-05308-sch016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/8643e3c9feb8/molecules-14-05308-sch017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/eee58328c52f/molecules-14-05308-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/792da8e8fa16/molecules-14-05308-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/5941700ba2e8/molecules-14-05308-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/efbc9632db98/molecules-14-05308-sch002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/2c95ae76c014/molecules-14-05308-sch003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/5e05d6d7cae6/molecules-14-05308-sch004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/c26712cd1f05/molecules-14-05308-sch005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/2fc27710cbd8/molecules-14-05308-sch006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/ae79a0c83567/molecules-14-05308-sch007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/7fb198699cac/molecules-14-05308-sch008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/7e608554ce7a/molecules-14-05308-sch009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/bd35d2e1daf5/molecules-14-05308-sch010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/41776a39e7ca/molecules-14-05308-sch011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/1c70c2ca32fb/molecules-14-05308-sch012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/637ad0773efa/molecules-14-05308-sch013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/e9cf2d7ca69d/molecules-14-05308-sch014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/54a293b303f9/molecules-14-05308-sch015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/548214c61f44/molecules-14-05308-sch016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/629f/6254800/8643e3c9feb8/molecules-14-05308-sch017.jpg

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本文引用的文献

1
Molecular iodine-mediated cyclization of tethered heteroatom-containing alkenyl or alkynyl systems.分子碘介导的含杂原子的烯基或炔基体系的连接环化反应。
Molecules. 2009 Nov 25;14(12):4814-37. doi: 10.3390/molecules14124814.
2
First detection of the plasmid-mediated quinolone resistance determinant qnrA in Enterobacteriaceae clinical isolates in Japan.在日本肠杆菌科临床分离株中首次检测到质粒介导的喹诺酮耐药决定簇qnrA。
Int J Antimicrob Agents. 2007 Jun;29(6):738-9. doi: 10.1016/j.ijantimicag.2007.01.010. Epub 2007 Mar 19.
3
Iodo- and bromo-enolcyclization of 2-(2-propenyl)cyclohexanediones and 2-(2-propenyl)cyclohexenone derivatives using iodine in methanol and pyridinium hydrobromide perbromide in dichloromethane.
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Org Biomol Chem. 2005 Jul 7;3(13):2469-75. doi: 10.1039/b505491e. Epub 2005 May 31.