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拉曼光谱研究锑酸盐矿物罗美石。

Raman spectroscopic study of the antimonate mineral roméite.

机构信息

Inorganic Materials Research Program, School of Physical and Chemical Sciences, Queensland University of Technology, GPO Box 2434, Brisbane, Queensland 4001, Australia.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2010 Feb;75(2):637-9. doi: 10.1016/j.saa.2009.11.031. Epub 2009 Nov 18.

Abstract

Raman spectroscopy has been sued to study the antimony containing mineral roméite Ca(2)Sb(2)O(6)(OH,F,O) from three different origins. Roméite is a calcium antimonate mineral of the pyrochlore group. An intense Raman band at approximately 518 cm(-1) for roméite is assigned to the SbO nu(1) symmetric stretching mode and the band at 466 cm(-1) to the SbO nu(3) antisymmetric stretching mode. The Raman band at 303 cm(-1) is attributed to the OSbO bending mode. Some variation in band positions is observed and is attributed to the variation in composition between the three mineral samples.

摘要

拉曼光谱已被用于研究来自三个不同产地的含锑矿物罗镁石 Ca(2)Sb(2)O(6)(OH,F,O)。罗镁石是烧绿石族的一种钙锑矿。罗镁石在约 518 cm(-1)处的强拉曼带归因于 SbO nu(1)对称伸缩模式,在 466 cm(-1)处的带归因于 SbO nu(3)反对称伸缩模式。303 cm(-1)处的拉曼带归因于 OSbO 弯曲模式。观察到带位置的一些变化,这归因于三个矿物样品之间的组成变化。

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