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Formal synthesis of (+/-)-guanacastepene A.
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An anti-tetraamination of a 1,3-diene unit via cascade annulations of the azulenone scaffold with dicarbonyl azo-compounds.
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A concise synthetic route to the stereotetrad core of the briarane diterpenoids.
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Total synthesis of guanacastepene a: a route to enantiomeric control.
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1
Development of a catalytic enantioselective synthesis of the guanacastepene and heptemerone tricyclic core.
Tetrahedron. 2019 Jun 14;75(24):3166-3177. doi: 10.1016/j.tet.2019.02.053. Epub 2019 Feb 27.

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Structure-directed reversion in the pi-facial stereoselective alkylation of chiral bicyclic lactams.
J Org Chem. 2008 Oct 3;73(19):7756-63. doi: 10.1021/jo801665k. Epub 2008 Sep 3.
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On the origin of the stereoselectivity in the alkylation of oxazolopiperidone enolates.
J Am Chem Soc. 2006 May 24;128(20):6581-8. doi: 10.1021/ja055393m.
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Total synthesis of guanacastepene a: a route to enantiomeric control.
J Org Chem. 2005 Dec 23;70(26):10619-37. doi: 10.1021/jo051470k.

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