稠合薁酮骨架与二羰基偶氮化合物通过串联环加成反应对 1,3-二烯单元进行反四氨化反应。
An anti-tetraamination of a 1,3-diene unit via cascade annulations of the azulenone scaffold with dicarbonyl azo-compounds.
机构信息
Division of Chemistry, Graduate School of Science, Hokkaido University, Sapporo, 060-0810, Japan.
出版信息
Chem Commun (Camb). 2010 May 21;46(19):3304-5. doi: 10.1039/b926676c. Epub 2010 Mar 15.
DOI:10.1039/b926676c
PMID:20442894
Abstract
Dense and stereo-controlled integrations of C-N bonds on the azulenone scaffold are achieved by sequential (i) ene, (ii) [6 + 2]-cycloaddition, and (iii) hetero-conjugate addition reactions leading to a topologically complex bis-bridged skeleton.
摘要
通过顺序（i）烯反应、（ii）[6+2]-环加成反应和（iii）杂共轭加成反应，在薁酮骨架上实现了 C-N 键的密集和立体控制集成，生成了拓扑结构复杂的双桥接骨架。
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