基于柔性三齿配体和 Cu(II)离子的阳离子五核簇与二维聚合阴离子层的空前结合。
Unprecedented marriage of a cationic pentanuclear cluster and a 2D polymeric anionic layer based on a flexible tripodal ligand and a Cu(II) ion.
机构信息
College of Chemistry, Liaoning University, Shenyang 110036, People's Republic of China.
出版信息
Inorg Chem. 2010 Feb 1;49(3):769-71. doi: 10.1021/ic902262u.
PMID:20047290
Abstract
The anionic CdI(2)-type topological net, Cu(2)(tci)(2), and the pentanuclear copper cluster cation Cu(5)(tci)(2)(OH)(2)(H(2)O)(8) [tci = tris(2-carboxyethyl)isocyanurate] form a complementary 3D supramolecular framework. Interestingly, there exist centrosymmetric cyclic (H(2)O)(18) clusters in the cavities.
摘要
阴离子 CdI(2)-型拓扑网络 [Cu(2)(tci)(2)]（2-）和五核铜簇阳离子 [Cu(5)(tci)(2)(OH)(2)(H(2)O)(8)]（2+）[tci = 三（2-羧乙基）异氰尿酸]形成互补的 3D 超分子骨架。有趣的是，在空腔中存在对称循环的 (H(2)O)(18)簇。
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